STUDY ON THE EXTRACTION OF MOLYBDENUM(VI) WITH BIS-(2-ETHYLHEXYL)PHOSPHATE
Guoping Liu
Abstract
Guoping Liu
Abstract
Using dodecane as diluent ,the extraction behavior of molybdenum(Ⅵ) with Bis-(2-ethylhexyl) phosphate from nitric acid solution is studied.Temperature has evident effect on distribution ratio of molybdenum(Ⅵ) .There is obvious heat effect in the extraction process .From 3 mol/L HNO3 solution ,molybdenum(Ⅵ) is extracted in the form of MoO2+2.The composition of the extraction complex is MoO2(NO3)2·2D2EHPA. The extraction equilibrium is given.
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Using dodecane as diluent ,the extraction behavior of molybdenum(Ⅵ) with Bis-(2-ethylhexyl) phosphate from nitric acid solution is studied.Temperature has evident effect on distribution ratio of molybdenum(Ⅵ) .There is obvious heat effect in the extraction process .From 3 mol/L HNO3 solution ,molybdenum(Ⅵ) is extracted in the form of MoO2+2.The composition of the extraction complex is MoO2(NO3)2·2D2EHPA. The extraction equilibrium is given.
Key concepts: Molybdenum, Diluent, Extraction (chemistry), Phosphate, Nitric acid, Dodecane, Chemistry, Inorganic chemistry