2006•He'nan kexueRequires access

Synthesis and Crystal Structure of a 3-D Supramolecular Structure [Cd(C_6H_4O_2N)_2(H_2O)_4]

Jinghao Hao

Abstract

A supramolecular compand [Cd(C6H4O2N)2(H2O)4 ] was synthesized by the reaction of Cd(NO3) 2·6H2O and isonicotinic.The results of single-crystal X-ray diffraction revealed that it consists of [Cd(C6H4O2N)2(H2O)4 ] units in which the Cd(Ⅱ) ion is located in a slightly distorted octahedral center.Each unit is connedted by the OH...O hydrogen bonds to form a three-dimensional layered structure.

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Key concepts: Supramolecular chemistry, Crystallography, Crystal structure, Hydrogen bond, Octahedron, Chemistry, Ion, Isonicotinic acid