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Liquid-phase Beckmann rearrangement of cyclohexanone oxime into caprolactam

Sinopec Baling

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Abstract

The research progress in liquid-phase Beckmann rearrangement of cyclohexanone oxime into caprolactam was reviewed. The novel liquid-phase Beckmann rearrangement processes were introduced emphatically under solid acid catalyst like molecular sieve, catalyst system containing alkylated reagents and DMF, ionic liquid catalyst, supercritical water or CO_2. It was pointed out that the green technological process using novel catalysts, particularly ionic liquid catalysts, would have wonderful prospects.

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What this paper is about

The research progress in liquid-phase Beckmann rearrangement of cyclohexanone oxime into caprolactam was reviewed. The novel liquid-phase Beckmann rearrangement processes were introduced emphatically under solid acid catalyst like molecular sieve, catalyst system containing alkylated reagents and DMF, ionic liquid catalyst, supercritical water or CO_2. It was pointed out that the green technological process using novel catalysts, particularly ionic liquid catalysts, would have wonderful prospects.

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Available abstract

The research progress in liquid-phase Beckmann rearrangement of cyclohexanone oxime into caprolactam was reviewed. The novel liquid-phase Beckmann rearrangement processes were introduced emphatically under solid acid catalyst like molecular sieve, catalyst system containing alkylated reagents and DMF, ionic liquid catalyst, supercritical water or CO_2. It was pointed out that the green technological process using novel catalysts, particularly ionic liquid catalysts, would have wonderful prospects.

Key concepts: Beckmann rearrangement, Cyclohexanone oxime, Caprolactam, Catalysis, Chemistry, Ionic liquid, Oxime, Cyclohexanone

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Liquid-phase Beckmann rearrangement of cyclohexanone oxime into caprolactam — Research Paper | ScholarLens