2010Journal of Sichuan University of Science & EngineeringRequires access

Effect of Ru/ZrO_2·xH_2O Catalyst Preparation on Catalytic Performance for Ester Hydrogenation to Alcohol

Guangyin Fan

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Abstract

The Ru/ZrO2·xH2O catalyst prepared by co-precipitation method is able to effectively catalytic hydrogenation of methyl propionate to propanol alcohol with high yields.The catalyst was characterized by XRD and XPS.Effect of stirring rate,types of alkali hydroxide,pH value,caclined temperature and ruthenium loading on the properties of Ru/ZrO2·xH2O catalyst were studied.The results show that the activity and selectivity of the catalyst increase when increasing the rate of stirring and ruthenium loading,however,both the activity and selectivity decrease with increasing of the pH value and caclined temperature.

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What this paper is about

The Ru/ZrO2·xH2O catalyst prepared by co-precipitation method is able to effectively catalytic hydrogenation of methyl propionate to propanol alcohol with high yields.The catalyst was characterized by XRD and XPS.Effect of stirring rate,types of alkali hydroxide,pH value,caclined temperature and ruthenium loading on the properties of Ru/ZrO2·xH2O catalyst were studied.The results show that the activity and selectivity of the catalyst increase when increasing the rate of stirring and ruthenium loading,however,both the activity and selectivity decrease with increasing of the pH value and caclined temperature.

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Available abstract

The Ru/ZrO2·xH2O catalyst prepared by co-precipitation method is able to effectively catalytic hydrogenation of methyl propionate to propanol alcohol with high yields.The catalyst was characterized by XRD and XPS.Effect of stirring rate,types of alkali hydroxide,pH value,caclined temperature and ruthenium loading on the properties of Ru/ZrO2·xH2O catalyst were studied.The results show that the activity and selectivity of the catalyst increase when increasing the rate of stirring and ruthenium loading,however,both the activity and selectivity decrease with increasing of the pH value and caclined temperature.

Key concepts: Catalysis, Ruthenium, Selectivity, Chemistry, Inorganic chemistry, Alcohol, X-ray photoelectron spectroscopy, Precipitation

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