ScholarLens Back to search
2012•Fain kemikaruRequires access

Oxidation of Cyclohexane Catalyzed by NHPI and CoSPc

Yuzhi Xiang

Open publisher page 0 citations

Abstract

The oxidation of cyclohexane catalyzed by N-hydroxyphthalimide(NHPI) and cobalt sulphonated phthalocyanine(CoSPc) was investigated,in which GC was used to analyze the composition of oxidation products.According to the standard sample,in addition to the normal products,cyclohexanone and cyclohexanol,cyclohexanol acetate was also found and verified.The effect of reaction time,temperature,the amount of NHPI and/or CoSPc on the oxidation reaction was examined,and the optimal reaction conditions of cyclohexane oxidation were as follows: reaction time 2 h,reaction temperature 80 ℃,n(cyclohexane)∶ n(NHPI)=10∶ 1,n(NHPI)∶ n(CoSPc)=6∶ 1.Under the optimal conditions,10.5% yield of cyclohexanone,1.1% of cyclohexanol and 0.4% of cyclohexanol acetate were obtained,and the total yield reached 12.0%.

About this research paper

What this paper is about

The oxidation of cyclohexane catalyzed by N-hydroxyphthalimide(NHPI) and cobalt sulphonated phthalocyanine(CoSPc) was investigated,in which GC was used to analyze the composition of oxidation products.According to the standard sample,in addition to the normal products,cyclohexanone and cyclohexanol,cyclohexanol acetate was also found and verified.The effect of reaction time,temperature,the amount of NHPI and/or CoSPc on the oxidation reaction was examined,and the optimal reaction conditions of cyclohexane oxidation were as follows: reaction time 2 h,reaction temperature 80 ℃,n(cyclohexane)∶ n(NHPI)=10∶ 1,n(NHPI)∶ n(CoSPc)=6∶ 1.Under the optimal conditions,10.5% yield of cyclohexanone,1.1% of cyclohexanol and 0.4% of cyclohexanol acetate were obtained,and the total yield reached 12.0%.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The oxidation of cyclohexane catalyzed by N-hydroxyphthalimide(NHPI) and cobalt sulphonated phthalocyanine(CoSPc) was investigated,in which GC was used to analyze the composition of oxidation products.According to the standard sample,in addition to the normal products,cyclohexanone and cyclohexanol,cyclohexanol acetate was also found and verified.The effect of reaction time,temperature,the amount of NHPI and/or CoSPc on the oxidation reaction was examined,and the optimal reaction conditions of cyclohexane oxidation were as follows: reaction time 2 h,reaction temperature 80 ℃,n(cyclohexane)∶ n(NHPI)=10∶ 1,n(NHPI)∶ n(CoSPc)=6∶ 1.Under the optimal conditions,10.5% yield of cyclohexanone,1.1% of cyclohexanol and 0.4% of cyclohexanol acetate were obtained,and the total yield reached 12.0%.

Key concepts: Cyclohexanol, Cyclohexane, Cyclohexanone, Yield (engineering), Catalysis, Chemistry, Cobalt, Reaction conditions

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Oxidation of Cyclohexane Catalyzed by NHPI and CoSPc — Research Paper | ScholarLens