ScholarLens Back to search
2004•Silicone MaterialRequires access

Synthesis of silicon-substituted polysilane from disilane fraction

Xing Xin

Open publisher page 0 citations

Abstract

Silicon substituted polysilane (SPS) was prepared by the disiane fraction produced in Direct Synthesis,via the redistribution of Si Cl with Grignard agent,obtained 11 dichlor 1122 tetramethyl disilane followed by sodium mediated condensations.The structure was confirmed by FT IR,UV and 29 Si CP MAS NMR.The results showed that the yield of 11 dichlor 1122 tetramethyl disilane was rested on the amount of Grignard agent.The yield of SPS was greatly affected by the reaction time,which was 4～5 hours.

About this research paper

What this paper is about

Silicon substituted polysilane (SPS) was prepared by the disiane fraction produced in Direct Synthesis,via the redistribution of Si Cl with Grignard agent,obtained 11 dichlor 1122 tetramethyl disilane followed by sodium mediated condensations.The structure was confirmed by FT IR,UV and 29 Si CP MAS NMR.The results showed that the yield of 11 dichlor 1122 tetramethyl disilane was rested on the amount of Grignard agent.The yield of SPS was greatly affected by the reaction time,which was 4～5 hours.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Silicon substituted polysilane (SPS) was prepared by the disiane fraction produced in Direct Synthesis,via the redistribution of Si Cl with Grignard agent,obtained 11 dichlor 1122 tetramethyl disilane followed by sodium mediated condensations.The structure was confirmed by FT IR,UV and 29 Si CP MAS NMR.The results showed that the yield of 11 dichlor 1122 tetramethyl disilane was rested on the amount of Grignard agent.The yield of SPS was greatly affected by the reaction time,which was 4～5 hours.

Key concepts: Disilane, Polysilane, Yield (engineering), Chemistry, Silicon, Fraction (chemistry), Redistribution (election), Nuclear chemistry

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Synthesis of silicon-substituted polysilane from disilane fraction — Research Paper | ScholarLens