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The performance of zinc electrode in electrolyte adding triethylamine,diethylamine

Ning Li

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Abstract

The influences of adding triethylamine[(C2H5)3N],diethylamine[(C2H5)2NH] and their mixture into alkaline electrolyte to the zinc electrode were studied.The mixing of triethylamine and diethylamine could improve the anti-corrosion and passivation performance of zinc electrode,the corrosion potential negative shift 0.01~0.02 V,the passivation potential increased 0.05~0.08 V,the reversibility was also improved,the effect was the best when V(KOH)∶V[(C2H5)3N]∶V[(C2H5)2NH]=100∶0.5∶0.5.Diethylamine was not suitable to use as additive individually since it would decrease the reversibility of zinc electrode.Triethylamine had no obvious improvement for zinc electrode performance as well.

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What this paper is about

The influences of adding triethylamine[(C2H5)3N],diethylamine[(C2H5)2NH] and their mixture into alkaline electrolyte to the zinc electrode were studied.The mixing of triethylamine and diethylamine could improve the anti-corrosion and passivation performance of zinc electrode,the corrosion potential negative shift 0.01~0.02 V,the passivation potential increased 0.05~0.08 V,the reversibility was also improved,the effect was the best when V(KOH)∶V[(C2H5)3N]∶V[(C2H5)2NH]=100∶0.5∶0.5.Diethylamine was not suitable to use as additive individually since it would decrease the reversibility of zinc electrode.Triethylamine had no obvious improvement for zinc electrode performance as well.

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Available abstract

The influences of adding triethylamine[(C2H5)3N],diethylamine[(C2H5)2NH] and their mixture into alkaline electrolyte to the zinc electrode were studied.The mixing of triethylamine and diethylamine could improve the anti-corrosion and passivation performance of zinc electrode,the corrosion potential negative shift 0.01~0.02 V,the passivation potential increased 0.05~0.08 V,the reversibility was also improved,the effect was the best when V(KOH)∶V[(C2H5)3N]∶V[(C2H5)2NH]=100∶0.5∶0.5.Diethylamine was not suitable to use as additive individually since it would decrease the reversibility of zinc electrode.Triethylamine had no obvious improvement for zinc electrode performance as well.

Key concepts: Diethylamine, Triethylamine, Passivation, Zinc, Electrolyte, Electrode, Inorganic chemistry, Corrosion

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