ScholarLens Back to search
2009•Rock and Mineral AnalysisRequires access

Determination of Tin in Antimony Trioxide by Hydride Generation-Atomic Fluorescence Spectrometry

Shufang Tang

Open publisher page 0 citations

Abstract

A method for the determination of tin in antimory trioxide by hydride generation-atomic fluorescence spectrometry was proposed,which base on the Sn(Ⅱ) reduced to SnH4 by potassium borohydride in the media of 10% hydrochloric acid.At 500 ℃ and in the existence of ammonium chloride and zinc,antimony was transformed to volatile antimony trichloride and them removed.Tin and zinc was formed to zinc-tin alloy and remained in the residue,so as to eliminate the interference of antimony on the determination of tin.The detection limit of the method for tin is 0.20 mg/kg and recovery is 91.0%～104.5% with precision of 3.73%RSD(n=7).

About this research paper

What this paper is about

A method for the determination of tin in antimory trioxide by hydride generation-atomic fluorescence spectrometry was proposed,which base on the Sn(Ⅱ) reduced to SnH4 by potassium borohydride in the media of 10% hydrochloric acid.At 500 ℃ and in the existence of ammonium chloride and zinc,antimony was transformed to volatile antimony trichloride and them removed.Tin and zinc was formed to zinc-tin alloy and remained in the residue,so as to eliminate the interference of antimony on the determination of tin.The detection limit of the method for tin is 0.20 mg/kg and recovery is 91.0%～104.5% with precision of 3.73%RSD(n=7).

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

A method for the determination of tin in antimory trioxide by hydride generation-atomic fluorescence spectrometry was proposed,which base on the Sn(Ⅱ) reduced to SnH4 by potassium borohydride in the media of 10% hydrochloric acid.At 500 ℃ and in the existence of ammonium chloride and zinc,antimony was transformed to volatile antimony trichloride and them removed.Tin and zinc was formed to zinc-tin alloy and remained in the residue,so as to eliminate the interference of antimony on the determination of tin.The detection limit of the method for tin is 0.20 mg/kg and recovery is 91.0%～104.5% with precision of 3.73%RSD(n=7).

Key concepts: Tin, Antimony, Chemistry, Antimony trioxide, Hydride, Zinc, Detection limit, Inorganic chemistry

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Determination of Tin in Antimony Trioxide by Hydride Generation-Atomic Fluorescence Spectrometry — Research Paper | ScholarLens