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Progress in Synthesis and Properties of Nitrogen-rich Compounds

Hong Wang

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Abstract

Nitrogen rich compounds are promising materials for gas generating pyrotechnic compositions. The synthesis and properties of nitrogen rich compounds with high nitrogen content,good thermal stability and high formation enthalpy on the basis of tetrazole,tetrazine and furazan structures are reviewed. The synthetic routes of 3,6 bis(1H 1,2,3,4 tetrazol 5 yl amino) 1,2,4,5 tetrazine(BTATZ),3,3′ azobis(6 amino 1,2,4,5 tetrazine)(DAAT),1,1′ dimethyl 5,5′ azotetrazole(DMATZ) and 3,6 bis(2H 5 tetrazol yl) 1,2,4,5 tetrazine (BTT) are mainly discussed.

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What this paper is about

Nitrogen rich compounds are promising materials for gas generating pyrotechnic compositions. The synthesis and properties of nitrogen rich compounds with high nitrogen content,good thermal stability and high formation enthalpy on the basis of tetrazole,tetrazine and furazan structures are reviewed. The synthetic routes of 3,6 bis(1H 1,2,3,4 tetrazol 5 yl amino) 1,2,4,5 tetrazine(BTATZ),3,3′ azobis(6 amino 1,2,4,5 tetrazine)(DAAT),1,1′ dimethyl 5,5′ azotetrazole(DMATZ) and 3,6 bis(2H 5 tetrazol yl) 1,2,4,5 tetrazine (BTT) are mainly discussed.

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Available abstract

Nitrogen rich compounds are promising materials for gas generating pyrotechnic compositions. The synthesis and properties of nitrogen rich compounds with high nitrogen content,good thermal stability and high formation enthalpy on the basis of tetrazole,tetrazine and furazan structures are reviewed. The synthetic routes of 3,6 bis(1H 1,2,3,4 tetrazol 5 yl amino) 1,2,4,5 tetrazine(BTATZ),3,3′ azobis(6 amino 1,2,4,5 tetrazine)(DAAT),1,1′ dimethyl 5,5′ azotetrazole(DMATZ) and 3,6 bis(2H 5 tetrazol yl) 1,2,4,5 tetrazine (BTT) are mainly discussed.

Key concepts: Tetrazine, Tetrazole, Nitrogen, Chemistry, Enthalpy, Thermal stability, Energetic material, Standard enthalpy of formation

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