2011Journal of Xiamen UniversityRequires access

The Electrophilic Aromatic Addition and Substitution Reactions of Metallabenzenes

Haiping Xia

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Abstract

Significant progress of the nucleophilic aromatic substitution(SNAr) reaction of metallabenzenes has been made in recent years.SNAr reaction not only can provide strong chemical support for the aromaticity of the metallabenzene rings but also obtain new interesting organometallic complexes.All the SNAr reactions of metallabenzenes,which have been reported,are reviewed in this article.

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What this paper is about

Significant progress of the nucleophilic aromatic substitution(SNAr) reaction of metallabenzenes has been made in recent years.SNAr reaction not only can provide strong chemical support for the aromaticity of the metallabenzene rings but also obtain new interesting organometallic complexes.All the SNAr reactions of metallabenzenes,which have been reported,are reviewed in this article.

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Available abstract

Significant progress of the nucleophilic aromatic substitution(SNAr) reaction of metallabenzenes has been made in recent years.SNAr reaction not only can provide strong chemical support for the aromaticity of the metallabenzene rings but also obtain new interesting organometallic complexes.All the SNAr reactions of metallabenzenes,which have been reported,are reviewed in this article.

Key concepts: Nucleophilic aromatic substitution, Electrophilic aromatic substitution, Chemistry, Radical-nucleophilic aromatic substitution, Substitution reaction, Aromaticity, Nucleophilic substitution, Electrophile

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