Catalytic Synthesis of Butanone 1,2-propanediol ketal by H_4SiW_(12)O_ (40)
Yumei Luo
Abstract
Yumei Luo
Abstract
Butanone 1,2-propanediol ketal was synthesized from butanone and 1,2-propanediol in the presence of H 4SiW 12O 40. The factors influencing the synthesis were discussed and the best conditions were found out. The optimum conditions were: molar ratio of butanone to 1,2-propanediol was 1∶1.5, the quantity of catalyst was equal to 1.5 % of feed stocks, and the reaction time was 1.5 h. H 4SiW 12O 40 is an excellent catalyst for synthesizing butanone 1,2-propanediol ketal and its yield can reach over 75.2 %.
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Butanone 1,2-propanediol ketal was synthesized from butanone and 1,2-propanediol in the presence of H 4SiW 12O 40. The factors influencing the synthesis were discussed and the best conditions were found out. The optimum conditions were: molar ratio of butanone to 1,2-propanediol was 1∶1.5, the quantity of catalyst was equal to 1.5 % of feed stocks, and the reaction time was 1.5 h. H 4SiW 12O 40 is an excellent catalyst for synthesizing butanone 1,2-propanediol ketal and its yield can reach over 75.2 %.
Key concepts: Butanone, Propanediol, Catalysis, Molar ratio, Yield (engineering), Chemistry, 1,3-Propanediol, Organic chemistry