2004•Chinese Journal of Spectroscopy LaboratoryRequires access

Inhibitory Kinetic Fluorimetric Determination of Trace Bromide

Feng wei Gao

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Abstract

A new kinetic fluorimetric method for the determination of trace bromine ion was developed based on the inhibition of bromide to oxidation of pyronine B by potassium bromate in dilute solution of phosphoric acid.The mechanism of the reaction was studied.Under the optimal conditions,the detection limit for bromine ion is 0.11μg/L.The linear range of the determination is 0.36? ?.33μg/L. The method was used to determine trace bromine ion in lake water and serum samples with satisfactory results.

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What this paper is about

A new kinetic fluorimetric method for the determination of trace bromine ion was developed based on the inhibition of bromide to oxidation of pyronine B by potassium bromate in dilute solution of phosphoric acid.The mechanism of the reaction was studied.Under the optimal conditions,the detection limit for bromine ion is 0.11μg/L.The linear range of the determination is 0.36? ?.33μg/L. The method was used to determine trace bromine ion in lake water and serum samples with satisfactory results.

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Available abstract

A new kinetic fluorimetric method for the determination of trace bromine ion was developed based on the inhibition of bromide to oxidation of pyronine B by potassium bromate in dilute solution of phosphoric acid.The mechanism of the reaction was studied.Under the optimal conditions,the detection limit for bromine ion is 0.11μg/L.The linear range of the determination is 0.36? ?.33μg/L. The method was used to determine trace bromine ion in lake water and serum samples with satisfactory results.

Key concepts: Bromine, Potassium bromate, Bromate, Chemistry, Bromide, Detection limit, Phosphoric acid, Potassium bromide

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