2014Chemical ReagentsRequires access

Synthesis of Mn-substituted Nickel Hydroxide

Yan Pan

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Abstract

Alpha phase nickel hydroxide has been widely investigated due to its properties of high discharge capacity. A series of battery material containing Mndopedalpha phase nickel hydroxide were synthesized under protective atmosphere. The effects of different Mn content and stirring intensity on coordination synthesis process were studied and the range of suitableprocess parameters was selected by orthogonal experiment. The process parameters were further optimized by uniform design method as the following results that Mn doped was amount 13. 3%,stirring speed was 32 r /S,pH value was12. 5 and the discharge capacity was 300 mAh /g. It is significantly higher than that of commercially available nickel hydroxide products and it has guiding significance for containing alpha phase nickel hydroxide battery materials in industrial production.

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What this paper is about

Alpha phase nickel hydroxide has been widely investigated due to its properties of high discharge capacity. A series of battery material containing Mndopedalpha phase nickel hydroxide were synthesized under protective atmosphere. The effects of different Mn content and stirring intensity on coordination synthesis process were studied and the range of suitableprocess parameters was selected by orthogonal experiment. The process parameters were further optimized by uniform design method as the following results that Mn doped was amount 13. 3%,stirring speed was 32 r /S,pH value was12. 5 and the discharge capacity was 300 mAh /g. It is significantly higher than that of commercially available nickel hydroxide products and it has guiding significance for containing alpha phase nickel hydroxide battery materials in industrial production.

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Available abstract

Alpha phase nickel hydroxide has been widely investigated due to its properties of high discharge capacity. A series of battery material containing Mndopedalpha phase nickel hydroxide were synthesized under protective atmosphere. The effects of different Mn content and stirring intensity on coordination synthesis process were studied and the range of suitableprocess parameters was selected by orthogonal experiment. The process parameters were further optimized by uniform design method as the following results that Mn doped was amount 13. 3%,stirring speed was 32 r /S,pH value was12. 5 and the discharge capacity was 300 mAh /g. It is significantly higher than that of commercially available nickel hydroxide products and it has guiding significance for containing alpha phase nickel hydroxide battery materials in industrial production.

Key concepts: Nickel, Hydroxide, Chemistry, Battery (electricity), Phase (matter), Inorganic chemistry, Organic chemistry, Quantum mechanics

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