2009•Journal of Shenyang University of Chemical TechnologyRequires access

Modified Montmorillonite and Unsaturated Polyester Resin Nanocomposites

Guosong Li

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Abstract

Stable sodium based montmorillonite suspension was prepared using natural calcium and sodium based bentonite as raw material.On this basis,the organic montmorillonite was prepared using Co2+ as the precipitant agent,and phthalic acid as modifier.The influence of the ratios of raw materials on modification of montmorillonite was studied.The X-ray diffraction results showed that the layer spacing of phthalic acid modified montmorillonite were increased to 1.318 23 nm,indicating that the organic matter entered into montmorillonite layers.Organic montmorillonite/unsaturated polyester resin composite was prepared and impact test showed that compared with pure unsaturated polyester resin,when the content of organic montmorillonite was 3 %,the impact strength was increased by 43.31 %.

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What this paper is about

Stable sodium based montmorillonite suspension was prepared using natural calcium and sodium based bentonite as raw material.On this basis,the organic montmorillonite was prepared using Co2+ as the precipitant agent,and phthalic acid as modifier.The influence of the ratios of raw materials on modification of montmorillonite was studied.The X-ray diffraction results showed that the layer spacing of phthalic acid modified montmorillonite were increased to 1.318 23 nm,indicating that the organic matter entered into montmorillonite layers.Organic montmorillonite/unsaturated polyester resin composite was prepared and impact test showed that compared with pure unsaturated polyester resin,when the content of organic montmorillonite was 3 %,the impact strength was increased by 43.31 %.

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Available abstract

Stable sodium based montmorillonite suspension was prepared using natural calcium and sodium based bentonite as raw material.On this basis,the organic montmorillonite was prepared using Co2+ as the precipitant agent,and phthalic acid as modifier.The influence of the ratios of raw materials on modification of montmorillonite was studied.The X-ray diffraction results showed that the layer spacing of phthalic acid modified montmorillonite were increased to 1.318 23 nm,indicating that the organic matter entered into montmorillonite layers.Organic montmorillonite/unsaturated polyester resin composite was prepared and impact test showed that compared with pure unsaturated polyester resin,when the content of organic montmorillonite was 3 %,the impact strength was increased by 43.31 %.

Key concepts: Montmorillonite, Phthalic acid, Bentonite, Materials science, Nanocomposite, Composite number, Polyester, Phthalic anhydride

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