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Preparation of Benzoic Acid via Oxidation of Benzaldehydes Using Na_2WO_4·2H_2O-H_2O_2 as a Catalyst

Dong‐Sheng Li

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Abstract

Benzoic acid was synthesized via oxidation of benzaldehydes using Na 2WO 4 ·2H 2O as a catalyst. It was investigated that the effects of hydrogen peroxide dosage, the reaction time, the amount of catalyst and acidic additive (NaHSO 4·H 2O) on the yield of benzoic acid; the effect of surfactant on yield of benzoic acid was discussed in the acid-free system. Non-ionic surfactant can effectively improve the yield of benzoic acid, such as the yield reached 90.03% by β-CD.

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What this paper is about

Benzoic acid was synthesized via oxidation of benzaldehydes using Na 2WO 4 ·2H 2O as a catalyst. It was investigated that the effects of hydrogen peroxide dosage, the reaction time, the amount of catalyst and acidic additive (NaHSO 4·H 2O) on the yield of benzoic acid; the effect of surfactant on yield of benzoic acid was discussed in the acid-free system. Non-ionic surfactant can effectively improve the yield of benzoic acid, such as the yield reached 90.03% by β-CD.

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Available abstract

Benzoic acid was synthesized via oxidation of benzaldehydes using Na 2WO 4 ·2H 2O as a catalyst. It was investigated that the effects of hydrogen peroxide dosage, the reaction time, the amount of catalyst and acidic additive (NaHSO 4·H 2O) on the yield of benzoic acid; the effect of surfactant on yield of benzoic acid was discussed in the acid-free system. Non-ionic surfactant can effectively improve the yield of benzoic acid, such as the yield reached 90.03% by β-CD.

Key concepts: Benzoic acid, Chemistry, Yield (engineering), Catalysis, Hydrogen peroxide, Pulmonary surfactant, Nuclear chemistry, Organic chemistry

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