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[The surface smoothing methods for three-dimensional fluorescence spectrometry based on Savitzky-Golay polynomial smoothing].

Shuxin Du, Yang-Feng Du, Xiaoli Wu

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Abstract

Spectral smoothing is commonly used as effective pretreatment methods in the spectral analysis. However, the conventional Savitzky-Golay polynomial smoothing methods used in two-dimensional spectral analysis can not be applied to three-dimensional spectrometry directly. In the present paper, a polynomial surface smoothing method is proposed, and the two-dimensional Savitzky-Golay polynomial smoothing methods are extended to three-dimensional fluorescence spectra. Experiment for detecting dissolved organ matter in water using three-dimensional fluorescence spectrometry was carried out, and experimental results show that the smoothing method for the three-dimensional fluorescence spectrum can effectively improve the modeling accuracy.

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What this paper is about

Spectral smoothing is commonly used as effective pretreatment methods in the spectral analysis. However, the conventional Savitzky-Golay polynomial smoothing methods used in two-dimensional spectral analysis can not be applied to three-dimensional spectrometry directly. In the present paper, a polynomial surface smoothing method is proposed, and the two-dimensional Savitzky-Golay polynomial smoothing methods are extended to three-dimensional fluorescence spectra. Experiment for detecting dissolved organ matter in water using three-dimensional fluorescence spectrometry was carried out, and experimental results show that the smoothing method for the three-dimensional fluorescence spectrum can effectively improve the modeling accuracy.

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Available abstract

Spectral smoothing is commonly used as effective pretreatment methods in the spectral analysis. However, the conventional Savitzky-Golay polynomial smoothing methods used in two-dimensional spectral analysis can not be applied to three-dimensional spectrometry directly. In the present paper, a polynomial surface smoothing method is proposed, and the two-dimensional Savitzky-Golay polynomial smoothing methods are extended to three-dimensional fluorescence spectra. Experiment for detecting dissolved organ matter in water using three-dimensional fluorescence spectrometry was carried out, and experimental results show that the smoothing method for the three-dimensional fluorescence spectrum can effectively improve the modeling accuracy.

Key concepts: Smoothing, Binary Golay code, Polynomial, Biological system, Algorithm, Analytical Chemistry (journal), Mathematics, Chemistry

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