2006PubMedRequires access

[Slurry sampling for direct determination of trace cadmium in amber by graphite furnace atomic absorption spectrometry].

Shizhong Chen, Deng-bo Lu

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Abstract

A method for the direct determination of trace cadmium in amber by graphite furnace atomic absorption spectrometry (GFAAS) with slurry sampling was described. Palladium nitrate was used as a matrix modifier to eliminate the interference. Slurry stability and the influences of the matrix modifier, ashing/atomization temperature and coexistent ions on analytical signals were investigated in detail. Under the optimized experimental conditions, the detection limit of this method was 9.4 ng x g(-1) with a precision of 6.1%.

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A method for the direct determination of trace cadmium in amber by graphite furnace atomic absorption spectrometry (GFAAS) with slurry sampling was described. Palladium nitrate was used as a matrix modifier to eliminate the interference. Slurry stability and the influences of the matrix modifier, ashing/atomization temperature and coexistent ions on analytical signals were investigated in detail. Under the optimized experimental conditions, the detection limit of this method was 9.4 ng x g(-1) with a precision of 6.1%.

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Available abstract

A method for the direct determination of trace cadmium in amber by graphite furnace atomic absorption spectrometry (GFAAS) with slurry sampling was described. Palladium nitrate was used as a matrix modifier to eliminate the interference. Slurry stability and the influences of the matrix modifier, ashing/atomization temperature and coexistent ions on analytical signals were investigated in detail. Under the optimized experimental conditions, the detection limit of this method was 9.4 ng x g(-1) with a precision of 6.1%.

Key concepts: Graphite furnace atomic absorption, Ashing, Slurry, Detection limit, Cadmium, Chemistry, Analytical Chemistry (journal), Matrix (chemical analysis)

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