2009•Gaofenzi cailiao kexue yu gongchengRequires access

Progresses in "Living"/Controlled Radical Polymerization of Vinyl Acetate

Fengqiu Chen

Abstract

The chain transfer and termination of vinyl acetate offen occur in polymerizatoin,so living/controlled radical polymerization of vinyl acetate is a large chanllenge.Different controlled radical polymerizations of vinyl acetate were summarized in this paper.Among these methods,RAFT mediated by xanthate and dithiocarbamate,cobalt mediated radical polymerization reallize the living/controlled radical polymerization of vinyl acetate.

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Key concepts: Vinyl acetate, Reversible addition−fragmentation chain-transfer polymerization, Xanthate, Living free-radical polymerization, Catalytic chain transfer, Radical polymerization, Chain transfer, Vinyl polymer