2010•Scientia Sinica ChimicaRequires access

Hydrothermal synthesis and effects on morphology of micro-/nanomaterials of hexagona β-Co(OH)_2

Wen Hua Yao

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Abstract

The hexagonal single-platelike or muti-platelikeβ-Co(OH) 2 have been successfully synthesized by changing the reaction condition through a simple surfactant-free and hydrothermal method.Under a suitable reaction condition,the perfect single-layer hexagonalβ-Co(OH) 2 platelets with highly crystalline nature can be obtained.The structure and morphology of the resultant products were characterized by using XRD,FESEM,TEM,HRTEM and Selected-Area Electron Diffraction(SAED) .The results show that the morphology and structure of the obtained products can be strongly influenced by changing the reaction condition,such as:Co(NO3) 2 concentrations,reaction temperature and composition of solutions(addition of isopropyl alcohol) .

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What this paper is about

The hexagonal single-platelike or muti-platelikeβ-Co(OH) 2 have been successfully synthesized by changing the reaction condition through a simple surfactant-free and hydrothermal method.Under a suitable reaction condition,the perfect single-layer hexagonalβ-Co(OH) 2 platelets with highly crystalline nature can be obtained.The structure and morphology of the resultant products were characterized by using XRD,FESEM,TEM,HRTEM and Selected-Area Electron Diffraction(SAED) .The results show that the morphology and structure of the obtained products can be strongly influenced by changing the reaction condition,such as:Co(NO3) 2 concentrations,reaction temperature and composition of solutions(addition of isopropyl alcohol) .

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Available abstract

The hexagonal single-platelike or muti-platelikeβ-Co(OH) 2 have been successfully synthesized by changing the reaction condition through a simple surfactant-free and hydrothermal method.Under a suitable reaction condition,the perfect single-layer hexagonalβ-Co(OH) 2 platelets with highly crystalline nature can be obtained.The structure and morphology of the resultant products were characterized by using XRD,FESEM,TEM,HRTEM and Selected-Area Electron Diffraction(SAED) .The results show that the morphology and structure of the obtained products can be strongly influenced by changing the reaction condition,such as:Co(NO3) 2 concentrations,reaction temperature and composition of solutions(addition of isopropyl alcohol) .

Key concepts: High-resolution transmission electron microscopy, Selected area diffraction, Hydrothermal circulation, Morphology (biology), Nanomaterials, Transmission electron microscopy, Chemical engineering, Hexagonal crystal system

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