Investigation on the Effect of Calcined-gypsum on the Early Hydration of Portland Cement
Hou Guihua
Abstract
Hou Guihua
Abstract
By experiment methods of DTA,XRD,IR,Chemical combined water analysis,Ca(OH)2 content and so forth,the effect of gypsum and calcined-gpysum on the early hydration of Portland Cement was investigated. The result showed that the hydrat product of the cement added calcined-gypsum has more Ca(OH)2 content during whole hydrating stage,less chemical combined water before 1 day and more after 1 day,and ettingite can not formed before 1 day comparaed with adding gypsum, .The reserch indicated that adding calcined-gypsum instead gypsum to cement can reinforce the early strength of cement, because the aluminate phase present in clinker can not hydrat to form ettringite during 1 day due to low dissolution rate of calcined-gypsum, so retarding action of ettingite on clinker hydration is decresed, the whole clinker mineral hydration is accelerated, the paste strength is incresed.
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By experiment methods of DTA,XRD,IR,Chemical combined water analysis,Ca(OH)2 content and so forth,the effect of gypsum and calcined-gpysum on the early hydration of Portland Cement was investigated. The result showed that the hydrat product of the cement added calcined-gypsum has more Ca(OH)2 content during whole hydrating stage,less chemical combined water before 1 day and more after 1 day,and ettingite can not formed before 1 day comparaed with adding gypsum, .The reserch indicated that adding calcined-gypsum instead gypsum to cement can reinforce the early strength of cement, because the aluminate phase present in clinker can not hydrat to form ettringite during 1 day due to low dissolution rate of calcined-gypsum, so retarding action of ettingite on clinker hydration is decresed, the whole clinker mineral hydration is accelerated, the paste strength is incresed.
Key concepts: Gypsum, Ettringite, Clinker (cement), Calcination, Cement, Portland cement, Materials science, Dissolution