Adsorption of Cu~(2+) on Nano-hydroxyapatite
Liuming Wu
Abstract
Liuming Wu
Abstract
Nano-hydroxyapatite synthesized by sol-gel technique was used to adsorb Cu2+ from aqueous solution.The effects of reaction time,pH and initial concentration of Cu2+ on the adsorption were investigated,and the adsorption mechanism was discussed.The results show that the adsorption quantity increases linearly from pH 4.5 to 7.5;the adsorption equilibrium can be achieved in 60min,when pH is higher than 7.5,Cu2+ is almost completely removed,and the maximum adsorption capacity is 51.28mg/g.n-HAP is an effective adsorbent for Cu2+,and the adsorption is a process of Langmuir adsorption isotherms,following the pseudo-second-order kinetic equation.
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Nano-hydroxyapatite synthesized by sol-gel technique was used to adsorb Cu2+ from aqueous solution.The effects of reaction time,pH and initial concentration of Cu2+ on the adsorption were investigated,and the adsorption mechanism was discussed.The results show that the adsorption quantity increases linearly from pH 4.5 to 7.5;the adsorption equilibrium can be achieved in 60min,when pH is higher than 7.5,Cu2+ is almost completely removed,and the maximum adsorption capacity is 51.28mg/g.n-HAP is an effective adsorbent for Cu2+,and the adsorption is a process of Langmuir adsorption isotherms,following the pseudo-second-order kinetic equation.
Key concepts: Adsorption, Aqueous solution, Nano-, Langmuir adsorption model, Chemistry, Chemical engineering, Kinetics, Materials science