2007•Transactions of Shenyang Ligong UniversityRequires access

A Study on the Adsorption Behavior of Fulvic Acid for Iron

Yan He

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Abstract

The virbrating adsorption method is used to study the adsorption mechanism of Fe3+.Meanwhile,the effects of time,pH and temperature are also investigated.The result shows that,when pH=4.5~6.5,adsorption is larger and stable and does not vary with the variable pH.When pH=5,the amount of absorption becomes bigger with the longer time,and through about 200 minutes the adsorption balance can be obtained.When pH=3,Fe3+ can be easily desorbed from FA,and through about 180 minutes the desorption balance can be obtained.From the isothermal adsorption curve,we can find that the adsorption of Fe3+ on fulvic acid is an endothermic process and also in coincidence with the Langmiur and Freundlich adsorption isotherms model.The adsorption caloric△H is 8.009 1 kJ·mol-1.

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The virbrating adsorption method is used to study the adsorption mechanism of Fe3+.Meanwhile,the effects of time,pH and temperature are also investigated.The result shows that,when pH=4.5~6.5,adsorption is larger and stable and does not vary with the variable pH.When pH=5,the amount of absorption becomes bigger with the longer time,and through about 200 minutes the adsorption balance can be obtained.When pH=3,Fe3+ can be easily desorbed from FA,and through about 180 minutes the desorption balance can be obtained.From the isothermal adsorption curve,we can find that the adsorption of Fe3+ on fulvic acid is an endothermic process and also in coincidence with the Langmiur and Freundlich adsorption isotherms model.The adsorption caloric△H is 8.009 1 kJ·mol-1.

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Available abstract

The virbrating adsorption method is used to study the adsorption mechanism of Fe3+.Meanwhile,the effects of time,pH and temperature are also investigated.The result shows that,when pH=4.5~6.5,adsorption is larger and stable and does not vary with the variable pH.When pH=5,the amount of absorption becomes bigger with the longer time,and through about 200 minutes the adsorption balance can be obtained.When pH=3,Fe3+ can be easily desorbed from FA,and through about 180 minutes the desorption balance can be obtained.From the isothermal adsorption curve,we can find that the adsorption of Fe3+ on fulvic acid is an endothermic process and also in coincidence with the Langmiur and Freundlich adsorption isotherms model.The adsorption caloric△H is 8.009 1 kJ·mol-1.

Key concepts: Adsorption, Freundlich equation, Chemistry, Endothermic process, Isothermal process, Desorption, Inorganic chemistry, Absorption (acoustics)

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