2011China Pulp & Paper IndustryRequires access

An empirical model of methanol formation during oxygen delignification of wheat straw pulp

Li‐Min Fu

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Abstract

The formation rule of methanol during oxygen delignification (OD) of wheat straw pulp was studied in this paper.It was found that methanol formation is linear to active alkali dosage,oxygen pressure,reaction temperature,and temperature holding time,from which an e mpi r ical model,i.e.,CMethanol=α·(AA)~(1/2)·(Tm-)·(PO2)n·Log(0.2547t+1) was established.The results show that the present model has a good correlation (R 2=0.977) with the experimental data for predicting the formation amount of methanol during delignification.So,it will be a good guidance for aiming at reducing the methanol formation in the oxygen delignification of wheat straw pulp.

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What this paper is about

The formation rule of methanol during oxygen delignification (OD) of wheat straw pulp was studied in this paper.It was found that methanol formation is linear to active alkali dosage,oxygen pressure,reaction temperature,and temperature holding time,from which an e mpi r ical model,i.e.,CMethanol=α·(AA)~(1/2)·(Tm-)·(PO2)n·Log(0.2547t+1) was established.The results show that the present model has a good correlation (R 2=0.977) with the experimental data for predicting the formation amount of methanol during delignification.So,it will be a good guidance for aiming at reducing the methanol formation in the oxygen delignification of wheat straw pulp.

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Available abstract

The formation rule of methanol during oxygen delignification (OD) of wheat straw pulp was studied in this paper.It was found that methanol formation is linear to active alkali dosage,oxygen pressure,reaction temperature,and temperature holding time,from which an e mpi r ical model,i.e.,CMethanol=α·(AA)~(1/2)·(Tm-)·(PO2)n·Log(0.2547t+1) was established.The results show that the present model has a good correlation (R 2=0.977) with the experimental data for predicting the formation amount of methanol during delignification.So,it will be a good guidance for aiming at reducing the methanol formation in the oxygen delignification of wheat straw pulp.

Key concepts: Methanol, Straw, Chemistry, Pulp (tooth), Oxygen, Kappa number, Pulp and paper industry, Inorganic chemistry

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