2004Chinese Journal of Spectroscopy LaboratoryRequires access

Spectrophotometric Determination of Palladium with p-Sulfobenzylidene-Rhodanine

Yang Li

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Abstract

In the hydrochloric acid solution,p-sulfobenzylidene-rhodanine(SBDR) reacts with palladium to form a stable 2∶1 color complex with the molar absorptivity of 5.79×10 4L·mol -1·cm -1 at 530nm.Beer's law is obeyed in the range of 0.2—50μg/25mL.This method was applied to the determination of palladium in catalyst with good results.

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In the hydrochloric acid solution,p-sulfobenzylidene-rhodanine(SBDR) reacts with palladium to form a stable 2∶1 color complex with the molar absorptivity of 5.79×10 4L·mol -1·cm -1 at 530nm.Beer's law is obeyed in the range of 0.2—50μg/25mL.This method was applied to the determination of palladium in catalyst with good results.

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Available abstract

In the hydrochloric acid solution,p-sulfobenzylidene-rhodanine(SBDR) reacts with palladium to form a stable 2∶1 color complex with the molar absorptivity of 5.79×10 4L·mol -1·cm -1 at 530nm.Beer's law is obeyed in the range of 0.2—50μg/25mL.This method was applied to the determination of palladium in catalyst with good results.

Key concepts: Rhodanine, Palladium, Molar absorptivity, Hydrochloric acid, Chemistry, Nuclear chemistry, Spectrophotometry, Color reaction

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