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Catalytic Synthesis of DOP by Heterogeneous Supported Heteropoly Acid Catalyst TiSiW_(12)O_(40)/TiO_2

Hong Guo

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Abstract

Heterogeneous supported heteropoly acid catalyst TiSiW\-\{12\}O\-\{40\}/TiO\-2 was prepared and used in heterogeneous catalytic synthesizing di(2 ethylhexyl) phthalate (DOP). This catalyst showed many advantages compared with sulphuric acid catalyst, for example, it can decrease corrosion of equipments and environmental pollution, higher esterification conversion. The treating the products is easy to operate and the catalyst may be used repeatedly.

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What this paper is about

Heterogeneous supported heteropoly acid catalyst TiSiW\-\{12\}O\-\{40\}/TiO\-2 was prepared and used in heterogeneous catalytic synthesizing di(2 ethylhexyl) phthalate (DOP). This catalyst showed many advantages compared with sulphuric acid catalyst, for example, it can decrease corrosion of equipments and environmental pollution, higher esterification conversion. The treating the products is easy to operate and the catalyst may be used repeatedly.

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Available abstract

Heterogeneous supported heteropoly acid catalyst TiSiW\-\{12\}O\-\{40\}/TiO\-2 was prepared and used in heterogeneous catalytic synthesizing di(2 ethylhexyl) phthalate (DOP). This catalyst showed many advantages compared with sulphuric acid catalyst, for example, it can decrease corrosion of equipments and environmental pollution, higher esterification conversion. The treating the products is easy to operate and the catalyst may be used repeatedly.

Key concepts: Catalysis, Heteropoly acid, Chemistry, Heterogeneous catalysis, Solid acid, Phthalate, Environmental pollution, Nuclear chemistry

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