Solid-phase Synthesis of 2-Amino-5-chloropyridine Salicylaldehyde Schiff Base and its Complexes
Meng De-s
Abstract
Meng De-s
Abstract
2-Amino-5-chloropyridine salicylaldehyde Schiff base(HL = C12H9ClON2) was synthesized by the solid phase reaction of 2-amino-5-chloropyridine and salicylaldehyde at room temperature.Then inorganic salts with transition metal nickel dichloride(cobalt dichloride,copper acetate) were joined to grind,2-amino-5-chloropyridine salicylidene Schiff base metal complexes were obtained by the solid phase reaction.Finally,the structures of the complexes were characterized by elemental analysis,IR spectrum,UV spectrum,1HNMR,fluorescence spectrum and conductivity.The results show that their composition respectively are CuL2,NiL2,CoL2.
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2-Amino-5-chloropyridine salicylaldehyde Schiff base(HL = C12H9ClON2) was synthesized by the solid phase reaction of 2-amino-5-chloropyridine and salicylaldehyde at room temperature.Then inorganic salts with transition metal nickel dichloride(cobalt dichloride,copper acetate) were joined to grind,2-amino-5-chloropyridine salicylidene Schiff base metal complexes were obtained by the solid phase reaction.Finally,the structures of the complexes were characterized by elemental analysis,IR spectrum,UV spectrum,1HNMR,fluorescence spectrum and conductivity.The results show that their composition respectively are CuL2,NiL2,CoL2.
Key concepts: Salicylaldehyde, Chemistry, Schiff base, Copper, Cobalt, Elemental analysis, Metal, Inorganic chemistry