KINETICS OF COMPETITIVE CONSECUTIVE SECOND-ORDER ESTERIFICATION UNDER THE CONDITION OF PHASE-TRANSFER CATALYSIS
Caf Nanjing
Abstract
Caf Nanjing
Abstract
Frost and Schwemer's time ratio method was applied in the study of kinetics of competitive consecutive second order esterification of sodium dehydroabietate with 1.2-dibromoethane by the phase-transfer catalysis (PTC). Reaction rate constants and value of activation energy were estimated based on data obtained and the possible mechanism for the esterification between solid-liquid phase in the presence of phase transfer catalyst was also postulated.
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Frost and Schwemer's time ratio method was applied in the study of kinetics of competitive consecutive second order esterification of sodium dehydroabietate with 1.2-dibromoethane by the phase-transfer catalysis (PTC). Reaction rate constants and value of activation energy were estimated based on data obtained and the possible mechanism for the esterification between solid-liquid phase in the presence of phase transfer catalyst was also postulated.
Key concepts: Chemistry, Catalysis, Kinetics, Phase (matter), Reaction rate constant, Activation energy, Organic chemistry, Physics