1992Linchan huaxue yu gongyeRequires access

KINETICS OF COMPETITIVE CONSECUTIVE SECOND-ORDER ESTERIFICATION UNDER THE CONDITION OF PHASE-TRANSFER CATALYSIS

Caf Nanjing

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Abstract

Frost and Schwemer's time ratio method was applied in the study of kinetics of competitive consecutive second order esterification of sodium dehydroabietate with 1.2-dibromoethane by the phase-transfer catalysis (PTC). Reaction rate constants and value of activation energy were estimated based on data obtained and the possible mechanism for the esterification between solid-liquid phase in the presence of phase transfer catalyst was also postulated.

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What this paper is about

Frost and Schwemer's time ratio method was applied in the study of kinetics of competitive consecutive second order esterification of sodium dehydroabietate with 1.2-dibromoethane by the phase-transfer catalysis (PTC). Reaction rate constants and value of activation energy were estimated based on data obtained and the possible mechanism for the esterification between solid-liquid phase in the presence of phase transfer catalyst was also postulated.

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Available abstract

Frost and Schwemer's time ratio method was applied in the study of kinetics of competitive consecutive second order esterification of sodium dehydroabietate with 1.2-dibromoethane by the phase-transfer catalysis (PTC). Reaction rate constants and value of activation energy were estimated based on data obtained and the possible mechanism for the esterification between solid-liquid phase in the presence of phase transfer catalyst was also postulated.

Key concepts: Chemistry, Catalysis, Kinetics, Phase (matter), Reaction rate constant, Activation energy, Organic chemistry, Physics

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KINETICS OF COMPETITIVE CONSECUTIVE SECOND-ORDER ESTERIFICATION UNDER THE CONDITION OF PHASE-TRANSFER CATALYSIS — Research Paper | ScholarLens