2012Journal of Solid Rocket TechnologyRequires access

Energy characteristics calculation of insensitive and minimum smoke GAP solid propellant

WU Jing-han

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Abstract

The energy characteristics of monopropellants and insensitive minimum smoke GAP propellants containing seven kinds of insensitive oxidizers and three insensitive energetic plasticizers,such as N-guanylureadinitramide(FOX-12),1,1-diamino-2,2-dinitroethylene(FOX-7),3-nitro-1,2,4-triazole-5-ketone(NTO),triaminotrinitrobenzene(TATB),3,4-dinitrofurazanfuroxan(DNTF),cyclotr imethylene trinitramine(RDX),ammonium dinitramide(ADN),1,2,4-butantriol trinitrate(BTTN),triethylene glycol dinitrate(TEGDN),trimethylolethane trinitrate(TMETN) and N-butyl-2-nitrate ethyl nitramine(Bu-NENA) were calculated by propellant energy calculation program.The calculation results show that the standard theoretical specific impulse(Isp) of monopropellant containing DNTF and RDX are 2 696.4 N·s/kg and 2 610.2 N·s/kg respectively,which are superior to that of the other oxidizers above.After the GAP binder/DNTF/RDX/ADN/Al propellant formulation is determined,the Isp,characteristic velocity(C*) and density(ρ) gradually increase with the increasing content of DNTF.Therefore,introducing DNTF into propellant helps to improve the energy characteristics of the insensitive and minimum smoke GAP propellant.

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The energy characteristics of monopropellants and insensitive minimum smoke GAP propellants containing seven kinds of insensitive oxidizers and three insensitive energetic plasticizers,such as N-guanylureadinitramide(FOX-12),1,1-diamino-2,2-dinitroethylene(FOX-7),3-nitro-1,2,4-triazole-5-ketone(NTO),triaminotrinitrobenzene(TATB),3,4-dinitrofurazanfuroxan(DNTF),cyclotr imethylene trinitramine(RDX),ammonium dinitramide(ADN),1,2,4-butantriol trinitrate(BTTN),triethylene glycol dinitrate(TEGDN),trimethylolethane trinitrate(TMETN) and N-butyl-2-nitrate ethyl nitramine(Bu-NENA) were calculated by propellant energy calculation program.The calculation results show that the standard theoretical specific impulse(Isp) of monopropellant containing DNTF and RDX are 2 696.4 N·s/kg and 2 610.2 N·s/kg respectively,which are superior to that of the other oxidizers above.After the GAP binder/DNTF/RDX/ADN/Al propellant formulation is determined,the Isp,characteristic velocity(C*) and density(ρ) gradually increase with the increasing content of DNTF.Therefore,introducing DNTF into propellant helps to improve the energy characteristics of the insensitive and minimum smoke GAP propellant.

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Available abstract

The energy characteristics of monopropellants and insensitive minimum smoke GAP propellants containing seven kinds of insensitive oxidizers and three insensitive energetic plasticizers,such as N-guanylureadinitramide(FOX-12),1,1-diamino-2,2-dinitroethylene(FOX-7),3-nitro-1,2,4-triazole-5-ketone(NTO),triaminotrinitrobenzene(TATB),3,4-dinitrofurazanfuroxan(DNTF),cyclotr imethylene trinitramine(RDX),ammonium dinitramide(ADN),1,2,4-butantriol trinitrate(BTTN),triethylene glycol dinitrate(TEGDN),trimethylolethane trinitrate(TMETN) and N-butyl-2-nitrate ethyl nitramine(Bu-NENA) were calculated by propellant energy calculation program.The calculation results show that the standard theoretical specific impulse(Isp) of monopropellant containing DNTF and RDX are 2 696.4 N·s/kg and 2 610.2 N·s/kg respectively,which are superior to that of the other oxidizers above.After the GAP binder/DNTF/RDX/ADN/Al propellant formulation is determined,the Isp,characteristic velocity(C*) and density(ρ) gradually increase with the increasing content of DNTF.Therefore,introducing DNTF into propellant helps to improve the energy characteristics of the insensitive and minimum smoke GAP propellant.

Key concepts: Propellant, Plasticizer, Explosive material, TATB, Specific impulse, Monopropellant, Materials science, Smoke

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