2012Engineering Journal of Wuhan UniversityRequires access

Adsorption properties of magnetic chitosan nanoparticle for humic acid and heavy metal ions

Shan Ma

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Abstract

The adsorption property of magnetic chitosan nanoparticle for humic acid and metal ions were studied.The adsorption performance of the absorbent on metal ions(Cu2+,Pb2+ and Cd2+) were affected by the presence of humic acid.The experimental results show that the highest adsorption capacity of 292 mg/g for humic acid is obtained at pH=11.The adsorption equilibrium was arrived in 15 min.The adsorption capacity for humic acid remained 60% of the initial adsorption capacity after being used five times.Furthermore,the Fe3O4-chitosan particles could be used to absorb metal ions after adsorption of humic acid.Compared with the results of metal ions alone adsorption,the adsorption capacities for Cu2+ and Pb2+ were decreased while the adsorption capacity for Cd2+ was greatly increased after adsorption of humic acid.

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The adsorption property of magnetic chitosan nanoparticle for humic acid and metal ions were studied.The adsorption performance of the absorbent on metal ions(Cu2+,Pb2+ and Cd2+) were affected by the presence of humic acid.The experimental results show that the highest adsorption capacity of 292 mg/g for humic acid is obtained at pH=11.The adsorption equilibrium was arrived in 15 min.The adsorption capacity for humic acid remained 60% of the initial adsorption capacity after being used five times.Furthermore,the Fe3O4-chitosan particles could be used to absorb metal ions after adsorption of humic acid.Compared with the results of metal ions alone adsorption,the adsorption capacities for Cu2+ and Pb2+ were decreased while the adsorption capacity for Cd2+ was greatly increased after adsorption of humic acid.

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Available abstract

The adsorption property of magnetic chitosan nanoparticle for humic acid and metal ions were studied.The adsorption performance of the absorbent on metal ions(Cu2+,Pb2+ and Cd2+) were affected by the presence of humic acid.The experimental results show that the highest adsorption capacity of 292 mg/g for humic acid is obtained at pH=11.The adsorption equilibrium was arrived in 15 min.The adsorption capacity for humic acid remained 60% of the initial adsorption capacity after being used five times.Furthermore,the Fe3O4-chitosan particles could be used to absorb metal ions after adsorption of humic acid.Compared with the results of metal ions alone adsorption,the adsorption capacities for Cu2+ and Pb2+ were decreased while the adsorption capacity for Cd2+ was greatly increased after adsorption of humic acid.

Key concepts: Adsorption, Humic acid, Metal ions in aqueous solution, Chitosan, Chemistry, Metal, Inorganic chemistry, Nuclear chemistry

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