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2000•Journal of Xiamen UniversityRequires access

Preparation of Mesoporous-Molecular-Sieve Supported Rhodium Phosphine Complex

Yuan You

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Abstract

The mesoporous molecular sieve (MCM 41) and the MCM 41 supported Rh PPh 3 complex (PPh 3: triphenylphosphine) were prepared and characterized by XRD and FT IR. The results showed that the MCM 41 supported Rh PPh 3 complex performed higher catalytic activity for hydroformylation of propene than some other molecular sieves supported catalysts under the same reaction conditions.

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What this paper is about

The mesoporous molecular sieve (MCM 41) and the MCM 41 supported Rh PPh 3 complex (PPh 3: triphenylphosphine) were prepared and characterized by XRD and FT IR. The results showed that the MCM 41 supported Rh PPh 3 complex performed higher catalytic activity for hydroformylation of propene than some other molecular sieves supported catalysts under the same reaction conditions.

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Available abstract

The mesoporous molecular sieve (MCM 41) and the MCM 41 supported Rh PPh 3 complex (PPh 3: triphenylphosphine) were prepared and characterized by XRD and FT IR. The results showed that the MCM 41 supported Rh PPh 3 complex performed higher catalytic activity for hydroformylation of propene than some other molecular sieves supported catalysts under the same reaction conditions.

Key concepts: Molecular sieve, Hydroformylation, Rhodium, Mesoporous material, Propene, Phosphine, MCM-41, Triphenylphosphine

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