2008•Wuji huaxue xuebaoRequires access

Synthesis and Crytal Structure of Schiff Base Ligand and Dinuclear Cu(II) Complex

Dai Mei

Open publisher page 0 citations

Abstract

Schiff base ligand C29H29N5O4 and a dinuclear complex C29H27N5O5Cu2 were synthesized, and characterized by elemental analysis, FTIR and single crystal X-ray diffraction. The crystal structures of the ligand and complex contain the two molecules possessing the same chemical structure with similar geometry,respectively. The two dinuclear molecules possessing similar structure were linked with intermolecular C-H…O hydrogen-bonds forming the dimer, and the dimer units are extended by the bridging hydrogen-bonds doubly between the ethanol and the dimer units forming one-dimensional chain. CCDC: 671402, ligand; 671401, complex.

About this research paper

What this paper is about

Schiff base ligand C29H29N5O4 and a dinuclear complex C29H27N5O5Cu2 were synthesized, and characterized by elemental analysis, FTIR and single crystal X-ray diffraction. The crystal structures of the ligand and complex contain the two molecules possessing the same chemical structure with similar geometry,respectively. The two dinuclear molecules possessing similar structure were linked with intermolecular C-H…O hydrogen-bonds forming the dimer, and the dimer units are extended by the bridging hydrogen-bonds doubly between the ethanol and the dimer units forming one-dimensional chain. CCDC: 671402, ligand; 671401, complex.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Schiff base ligand C29H29N5O4 and a dinuclear complex C29H27N5O5Cu2 were synthesized, and characterized by elemental analysis, FTIR and single crystal X-ray diffraction. The crystal structures of the ligand and complex contain the two molecules possessing the same chemical structure with similar geometry,respectively. The two dinuclear molecules possessing similar structure were linked with intermolecular C-H…O hydrogen-bonds forming the dimer, and the dimer units are extended by the bridging hydrogen-bonds doubly between the ethanol and the dimer units forming one-dimensional chain. CCDC: 671402, ligand; 671401, complex.

Key concepts: Dimer, Schiff base, Hydrogen bond, Molecule, Crystal structure, Crystallography, Ligand (biochemistry), Chemistry

Related papers

Back to paper searchBrowse research topicsOriginal source
Synthesis and Crytal Structure of Schiff Base Ligand and Dinuclear Cu(II) Complex — Research Paper | ScholarLens