2004Journal of Instrumental AnalysisRequires access

Indirect Spectrophotometric Determination of Hydroxylamine Hydrochloride with Copper(II)-phosphate-molybdate Heteropoly Acid

Zhan Cheng Guo

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Abstract

An indirect spectrophotometric method for the determination of hydroxylamine hydrochloride was developed.It was based on the heteropoly blue,produced from the redox reaction of hydroxylamine hyˉdrochloride with copper(Ⅱ)-phosphate-molybdate heteropoly acid.Beer′s lawwas obeyed in the range of0to7.68μg/mLwith a correlation coefficient of0.9996.The RSD was0.43%(n=6).The method has been used to determine the industrial grade of hydroxylamine hydrochloride with satisfactory result.

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An indirect spectrophotometric method for the determination of hydroxylamine hydrochloride was developed.It was based on the heteropoly blue,produced from the redox reaction of hydroxylamine hyˉdrochloride with copper(Ⅱ)-phosphate-molybdate heteropoly acid.Beer′s lawwas obeyed in the range of0to7.68μg/mLwith a correlation coefficient of0.9996.The RSD was0.43%(n=6).The method has been used to determine the industrial grade of hydroxylamine hydrochloride with satisfactory result.

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Available abstract

An indirect spectrophotometric method for the determination of hydroxylamine hydrochloride was developed.It was based on the heteropoly blue,produced from the redox reaction of hydroxylamine hyˉdrochloride with copper(Ⅱ)-phosphate-molybdate heteropoly acid.Beer′s lawwas obeyed in the range of0to7.68μg/mLwith a correlation coefficient of0.9996.The RSD was0.43%(n=6).The method has been used to determine the industrial grade of hydroxylamine hydrochloride with satisfactory result.

Key concepts: Chemistry, Hydroxylamine Hydrochloride, Hydroxylamine, Molybdate, Copper, Phosphate, Molybdenum blue, Nuclear chemistry

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