2006•Acta Metallurgica SinicaRequires access

INFLUENCE OF SO_4~(2-) IN AQUEOUS SOLUTION CONTAINING Cl~- ON THE CRITICAL PITTING CORROSION TEMPERATURE OF 316 STAINLESS STEEL

Jin Chun Li

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Abstract

The influence of SO42- on the pitting corrosion behavior of 316 stainless steel has been studied by measuring the relationship of corrosion current and temperature in 0.5% Cl- solutions with different concentrations of SO42- at constant applied potentials. The results showed that with the increase of SO42- concentration, the passivation current increased and the open circuit potential decreased; When the concentration of SO42- was less (more) than 0.42%, the critical pitting temperature was lower (higher) than that without SO42-. The inhibition and acceleration effects of SO42- on the pitting corrosion were discussed by analyzing the mechanism of the ion-competitive adsorption.

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What this paper is about

The influence of SO42- on the pitting corrosion behavior of 316 stainless steel has been studied by measuring the relationship of corrosion current and temperature in 0.5% Cl- solutions with different concentrations of SO42- at constant applied potentials. The results showed that with the increase of SO42- concentration, the passivation current increased and the open circuit potential decreased; When the concentration of SO42- was less (more) than 0.42%, the critical pitting temperature was lower (higher) than that without SO42-. The inhibition and acceleration effects of SO42- on the pitting corrosion were discussed by analyzing the mechanism of the ion-competitive adsorption.

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Available abstract

The influence of SO42- on the pitting corrosion behavior of 316 stainless steel has been studied by measuring the relationship of corrosion current and temperature in 0.5% Cl- solutions with different concentrations of SO42- at constant applied potentials. The results showed that with the increase of SO42- concentration, the passivation current increased and the open circuit potential decreased; When the concentration of SO42- was less (more) than 0.42%, the critical pitting temperature was lower (higher) than that without SO42-. The inhibition and acceleration effects of SO42- on the pitting corrosion were discussed by analyzing the mechanism of the ion-competitive adsorption.

Key concepts: Materials science, Passivation, Pitting corrosion, Corrosion, Aqueous solution, Metallurgy, Adsorption, Open-circuit voltage

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INFLUENCE OF SO_4~(2-) IN AQUEOUS SOLUTION CONTAINING Cl~- ON THE CRITICAL PITTING CORROSION TEMPERATURE OF 316 STAINLESS STEEL — Research Paper | ScholarLens