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ChemInform Abstract: POSSIBILITY OF ARENONIUM ION FORMATION DURING DEHYDRATION OF 1,4,4‐TRISUBSTITUTED 2,5‐CYCLOHEXADIEN‐1‐OLS

V. A. Nikanorov, V.I. Rozenberg, G. V. Gavrilova, B. I. Ginzburg, O. A. Reutov

Abstract

Abstract Der Cyclohexadienylalkohol (I) wird beim Filtrieren seiner Lösung in Hexan über Silicagel dehydratisiert, und es entstehen das Trien (II) und das butylsubstituierte Xylol (III) im Verhältnis 2 : l. Die Dehydratisierung von (I) erfolgt auch spontan in Ether, wobei die Derivate (II) und (III) im Verhältnis 1.5 : l erhalten werden.

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Key concepts: Chemistry, Medicinal chemistry, Dehydration, Ether, Polymer chemistry, Organic chemistry, Biochemistry