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ChemInform Abstract: DIRECT ORTHO‐METALATION OF BENZYL ALCOHOLS. A NOVEL PREPARATION OF ORTHO‐SUBSTITUTED BENZYL ALCOHOLS

Norbert Meyer, Dieter Seebàch

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Abstract

Abstract Benzylalkohol (I) und andere Phenylcarbinole (VII), einschließlich α‐Tetralol (X), werden von überschüssigem Butyllithium/ Tetramethylethylendiamin zu Lithium‐ortho‐1ithioalkoholaten (II), (VIII) und (XI) doppelt deprotoniert.

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What this paper is about

Abstract Benzylalkohol (I) und andere Phenylcarbinole (VII), einschließlich α‐Tetralol (X), werden von überschüssigem Butyllithium/ Tetramethylethylendiamin zu Lithium‐ortho‐1ithioalkoholaten (II), (VIII) und (XI) doppelt deprotoniert.

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Available abstract

Abstract Benzylalkohol (I) und andere Phenylcarbinole (VII), einschließlich α‐Tetralol (X), werden von überschüssigem Butyllithium/ Tetramethylethylendiamin zu Lithium‐ortho‐1ithioalkoholaten (II), (VIII) und (XI) doppelt deprotoniert.

Key concepts: Metalation, Butyllithium, Chemistry, Lithium (medication), Organic chemistry, Medicinal chemistry, Psychiatry, Psychology

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ChemInform Abstract: DIRECT ORTHO‐METALATION OF BENZYL ALCOHOLS. A NOVEL PREPARATION OF ORTHO‐SUBSTITUTED BENZYL ALCOHOLS — Research Paper | ScholarLens