2015Physics and Chemistry of LiquidsRequires access

Prediction of the surface tension of cesium in the whole liquid range

Mehdi N. Bahadori, Z. Akbari

Open publisher page 2 citations

Abstract

Surface tension is an important quantity, both as physical and technological features. We applied the general form of Lennard-Jones potential model, LJ (m-n), and some thermodynamic arguments in the Kirkwood and Buff equation to calculate the surface tension of liquid cesium. To find out the surface tension in a wide temperature range, only pVT data are required. By this method, we investigated the influence of the potential model on the surface tension. For two selected potential models [LJ (6–3) and LJ (8.5–4)], the values of the calculated surface tension and the predicted surface energy agree with the experimental values.

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What this paper is about

Surface tension is an important quantity, both as physical and technological features. We applied the general form of Lennard-Jones potential model, LJ (m-n), and some thermodynamic arguments in the Kirkwood and Buff equation to calculate the surface tension of liquid cesium. To find out the surface tension in a wide temperature range, only pVT data are required. By this method, we investigated the influence of the potential model on the surface tension. For two selected potential models [LJ (6–3) and LJ (8.5–4)], the values of the calculated surface tension and the predicted surface energy agree with the experimental values.

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Available abstract

Surface tension is an important quantity, both as physical and technological features. We applied the general form of Lennard-Jones potential model, LJ (m-n), and some thermodynamic arguments in the Kirkwood and Buff equation to calculate the surface tension of liquid cesium. To find out the surface tension in a wide temperature range, only pVT data are required. By this method, we investigated the influence of the potential model on the surface tension. For two selected potential models [LJ (6–3) and LJ (8.5–4)], the values of the calculated surface tension and the predicted surface energy agree with the experimental values.

Key concepts: Surface tension, Chemistry, Thermodynamics, Maximum bubble pressure method, Caesium, Range (aeronautics), Surface (topology), Surface energy

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