2013•The Journal of Physical Chemistry CRequires access

Enhancement of Photovoltaic Performance of Dye-Sensitized Solar Cells by Modifying Tin Oxide Nanorods with Titanium Oxide Layer

Guanglu Shang, Jihuai Wu, Shen Tang, Lu Liu, Xiaopei Zhang

Open publisher page 58 citations

Abstract

Highly crystalline SnO 2 nanorods with lengths of about 200 nm and diameters of 40–80 nm are synthesized by a hydrothermal method. Because of an efficient electron transport channel along the one-dimensional structure, a dye-sensitized solar cell (DSSC) based on the SnO 2 nanorods shows a fast electron transport and a long electron lifetime, resulting in higher power conversion efficiency than the DSSC SnO 2 -based nanoparticles. To suppress charge recombination at SnO 2 nanorods and electrolyte/dye interfaces, we modify SnO 2 nanorod electrode with TiO 2 compact layer and TiCl 4 post-treatment, and the DSSC exhibits a power conversion efficiency of 4.67%.

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What this paper is about

Highly crystalline SnO 2 nanorods with lengths of about 200 nm and diameters of 40–80 nm are synthesized by a hydrothermal method. Because of an efficient electron transport channel along the one-dimensional structure, a dye-sensitized solar cell (DSSC) based on the SnO 2 nanorods shows a fast electron transport and a long electron lifetime, resulting in higher power conversion efficiency than the DSSC SnO 2 -based nanoparticles. To suppress charge recombination at SnO 2 nanorods and electrolyte/dye interfaces, we modify SnO 2 nanorod electrode with TiO 2 compact layer and TiCl 4 post-treatment, and the DSSC exhibits a power conversion efficiency of 4.67%.

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Available abstract

Highly crystalline SnO 2 nanorods with lengths of about 200 nm and diameters of 40–80 nm are synthesized by a hydrothermal method. Because of an efficient electron transport channel along the one-dimensional structure, a dye-sensitized solar cell (DSSC) based on the SnO 2 nanorods shows a fast electron transport and a long electron lifetime, resulting in higher power conversion efficiency than the DSSC SnO 2 -based nanoparticles. To suppress charge recombination at SnO 2 nanorods and electrolyte/dye interfaces, we modify SnO 2 nanorod electrode with TiO 2 compact layer and TiCl 4 post-treatment, and the DSSC exhibits a power conversion efficiency of 4.67%.

Key concepts: Dye-sensitized solar cell, Nanorod, Tin oxide, Materials science, Energy conversion efficiency, Electrolyte, Solar cell, Layer (electronics)

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