1974Journal of The Surface Finishing Society of JapanOpen access

Conversion Treatment of Aluminum and Aluminum Alloys with Ammoniacal Bath

Kaoru SAIKI, Yukio Ôkura

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Abstract

The authors studied the effects of various sorts of amines and ammonium salts upon the formation bohmite film from ammonium base bath by chemical conversion. The results obtained were as follows. (1) Triethanolamine formed a stable chelate compound which accelerated the formation of bohmite film. (2) Ammonium carbonate had good effects upon the continuance of bath composition by the following reactions: 2Al+(NH4)2CO3+3H2O→2NH4AlO2+CO2+3H2, 2NH4AlO2+H2O→Al2O3+2NH4OH, 2NH4OH+CO2→(NH4)2CO3+H2O, (3) The ammonium hydroxide bath containing triethanolamine and ammonium carbonate continuously formed a very stable böhmite film on Aluminum and Aluminum alloys having no bad odor.

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The authors studied the effects of various sorts of amines and ammonium salts upon the formation bohmite film from ammonium base bath by chemical conversion. The results obtained were as follows. (1) Triethanolamine formed a stable chelate compound which accelerated the formation of bohmite film. (2) Ammonium carbonate had good effects upon the continuance of bath composition by the following reactions: 2Al+(NH4)2CO3+3H2O→2NH4AlO2+CO2+3H2, 2NH4AlO2+H2O→Al2O3+2NH4OH, 2NH4OH+CO2→(NH4)2CO3+H2O, (3) The ammonium hydroxide bath containing triethanolamine and ammonium carbonate continuously formed a very stable böhmite film on Aluminum and Aluminum alloys having no bad odor.

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Available abstract

The authors studied the effects of various sorts of amines and ammonium salts upon the formation bohmite film from ammonium base bath by chemical conversion. The results obtained were as follows. (1) Triethanolamine formed a stable chelate compound which accelerated the formation of bohmite film. (2) Ammonium carbonate had good effects upon the continuance of bath composition by the following reactions: 2Al+(NH4)2CO3+3H2O→2NH4AlO2+CO2+3H2, 2NH4AlO2+H2O→Al2O3+2NH4OH, 2NH4OH+CO2→(NH4)2CO3+H2O, (3) The ammonium hydroxide bath containing triethanolamine and ammonium carbonate continuously formed a very stable böhmite film on Aluminum and Aluminum alloys having no bad odor.

Key concepts: Triethanolamine, Ammonium hydroxide, Ammonium, Aluminium, Chemistry, Ammonium carbonate, Inorganic chemistry, Base (topology)

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