Synthesis and Structure of Diacetato-[1-benzyloxy-1,1-bis(N-methylimdazol-2-yl)ethane]zinc(II)
Sue E. Boyd, Margaret M. Harding, IE Buys, Trevor W. Hambley
Abstract
Sue E. Boyd, Margaret M. Harding, IE Buys, Trevor W. Hambley
Abstract
The synthesis and single-crystal X-ray structure determination of the title compound are described. The crystals are monoclinic, P21/c, a 10.064(2), b 13.096(2), c 17.722(3) ?, ß 104.68(2)°; the structure was refined to a residual of 0.033 for 3138 independent observed reflections. The coordination about zinc is intermediate between four- and five-coordinate, and the angle between the planar imidazole groups is 14.9°.
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The synthesis and single-crystal X-ray structure determination of the title compound are described. The crystals are monoclinic, P21/c, a 10.064(2), b 13.096(2), c 17.722(3) ?, ß 104.68(2)°; the structure was refined to a residual of 0.033 for 3138 independent observed reflections. The coordination about zinc is intermediate between four- and five-coordinate, and the angle between the planar imidazole groups is 14.9°.
Key concepts: Monoclinic crystal system, Zinc, Crystal structure, Chemistry, Biocatalysis, Imidazole, Supramolecular chemistry, Crystallography