Rose Bengal Immobilized on Wool as an Efficiently “Green” Sensitizer for Photooxygenation Reactions
Yan Zhang, Wei Wang, He Xun, Sang Anguo
Abstract
Yan Zhang, Wei Wang, He Xun, Sang Anguo
Abstract
Abstract A new type of supported photosensitizer derived from renewable wool and Rose Bengal is described. The novel sensitizer could efficiently promote the photooxygenation of furan derivatives to the corresponding 5-hydroxy-2-(5H)-furanone in excellent yields, via singlet oxygen, using visible light as the energy source. The sensitizer could be easily recovered from the reaction mixture by a simple filtration. It is discovered that the recovered sensitizer can be reused four times.
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Abstract A new type of supported photosensitizer derived from renewable wool and Rose Bengal is described. The novel sensitizer could efficiently promote the photooxygenation of furan derivatives to the corresponding 5-hydroxy-2-(5H)-furanone in excellent yields, via singlet oxygen, using visible light as the energy source. The sensitizer could be easily recovered from the reaction mixture by a simple filtration. It is discovered that the recovered sensitizer can be reused four times.
Key concepts: Rose bengal, Photooxygenation, Chemistry, Photosensitizer, Singlet oxygen, Furan, Wool, Photochemistry