2012•Chemistry LettersRequires access

Rose Bengal Immobilized on Wool as an Efficiently “Green” Sensitizer for Photooxygenation Reactions

Yan Zhang, Wei Wang, He Xun, Sang Anguo

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Abstract

Abstract A new type of supported photosensitizer derived from renewable wool and Rose Bengal is described. The novel sensitizer could efficiently promote the photooxygenation of furan derivatives to the corresponding 5-hydroxy-2-(5H)-furanone in excellent yields, via singlet oxygen, using visible light as the energy source. The sensitizer could be easily recovered from the reaction mixture by a simple filtration. It is discovered that the recovered sensitizer can be reused four times.

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What this paper is about

Abstract A new type of supported photosensitizer derived from renewable wool and Rose Bengal is described. The novel sensitizer could efficiently promote the photooxygenation of furan derivatives to the corresponding 5-hydroxy-2-(5H)-furanone in excellent yields, via singlet oxygen, using visible light as the energy source. The sensitizer could be easily recovered from the reaction mixture by a simple filtration. It is discovered that the recovered sensitizer can be reused four times.

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Available abstract

Abstract A new type of supported photosensitizer derived from renewable wool and Rose Bengal is described. The novel sensitizer could efficiently promote the photooxygenation of furan derivatives to the corresponding 5-hydroxy-2-(5H)-furanone in excellent yields, via singlet oxygen, using visible light as the energy source. The sensitizer could be easily recovered from the reaction mixture by a simple filtration. It is discovered that the recovered sensitizer can be reused four times.

Key concepts: Rose bengal, Photooxygenation, Chemistry, Photosensitizer, Singlet oxygen, Furan, Wool, Photochemistry

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