Verbaspinoside, a New Iridoid Glycoside from Verbascum spinosum
Elefterios Kalpoutzakis, Nektarios Aligiannis, Sofia Mitakou, Alexios‐Léandros Skaltsounis
Abstract
Elefterios Kalpoutzakis, Nektarios Aligiannis, Sofia Mitakou, Alexios‐Léandros Skaltsounis
Abstract
A new iridoid glycoside, verbaspinoside (1), was isolated from the aerial parts of Verbascum spinosum. Its structure was elucidated on the basis of chemical and spectral data as 6-O-[(2' '-O-trans-cinnamoyl)-alpha-L-rhamnopyranosyl]-catalpol. Additionally, three known iridoids (aucubin, catalpol, and ajugol) and three phenylpropanoid glycosides [acteoside, angoroside A (2), and angoroside C (3)] were isolated and identified.
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A new iridoid glycoside, verbaspinoside (1), was isolated from the aerial parts of Verbascum spinosum. Its structure was elucidated on the basis of chemical and spectral data as 6-O-[(2' '-O-trans-cinnamoyl)-alpha-L-rhamnopyranosyl]-catalpol. Additionally, three known iridoids (aucubin, catalpol, and ajugol) and three phenylpropanoid glycosides [acteoside, angoroside A (2), and angoroside C (3)] were isolated and identified.
Key concepts: Catalpol, Aucubin, Iridoid, Verbascoside, Glycoside, Chemistry, Phenylpropanoid, Stereochemistry