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Effect of the Composition of Mixed Oils on the Phase Behavior and Solubilization Ability of Microemulsion Systems

Wei Liu, Jinling Chai, Lusheng Chen, Lei Xu, Meili Zhu, Jianjun Lu

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Abstract

The phase behavior and the solubilization ability of the microemulsion systems containing mixed oils: sodium lauryl sulfate (SDS) + butan-1-ol + oil mixture (hexane + decane, hexane + cyclohexane, hexane + methylbenzene, methylbenzene + decane, methylbenzene + cyclohexane and methylbenzene + tetrachloroethene) + NaCl aqueous solution were studied using the ε–β fishlike phase diagram method. The synergism in the solubilization ability was observed in the microemulsion systems containing mixtures of methylbenzene + hexane, methylbenzene + cyclohexane, and methylbenzene + tetrachloroethene, respectively. The solubility of the alcohol in the oil and aqueous phases and the composition of the interfacial layer in the microemulsion systems containing oil mixtures were also investigated.

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What this paper is about

The phase behavior and the solubilization ability of the microemulsion systems containing mixed oils: sodium lauryl sulfate (SDS) + butan-1-ol + oil mixture (hexane + decane, hexane + cyclohexane, hexane + methylbenzene, methylbenzene + decane, methylbenzene + cyclohexane and methylbenzene + tetrachloroethene) + NaCl aqueous solution were studied using the ε–β fishlike phase diagram method. The synergism in the solubilization ability was observed in the microemulsion systems containing mixtures of methylbenzene + hexane, methylbenzene + cyclohexane, and methylbenzene + tetrachloroethene, respectively. The solubility of the alcohol in the oil and aqueous phases and the composition of the interfacial layer in the microemulsion systems containing oil mixtures were also investigated.

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Available abstract

The phase behavior and the solubilization ability of the microemulsion systems containing mixed oils: sodium lauryl sulfate (SDS) + butan-1-ol + oil mixture (hexane + decane, hexane + cyclohexane, hexane + methylbenzene, methylbenzene + decane, methylbenzene + cyclohexane and methylbenzene + tetrachloroethene) + NaCl aqueous solution were studied using the ε–β fishlike phase diagram method. The synergism in the solubilization ability was observed in the microemulsion systems containing mixtures of methylbenzene + hexane, methylbenzene + cyclohexane, and methylbenzene + tetrachloroethene, respectively. The solubility of the alcohol in the oil and aqueous phases and the composition of the interfacial layer in the microemulsion systems containing oil mixtures were also investigated.

Key concepts: Microemulsion, Chemistry, Cyclohexane, Hexane, Decane, Solubility, Aqueous solution, Phase (matter)

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