2006•Acta Crystallographica Section C Crystal Structure CommunicationsRequires access

A hexagonal 2a,csuperstructure of Ba7F12Cl2

Anita Bernsteiner, F. Kubel

Abstract

Hydrothermal synthesis yielded crystals of heptabarium dodecafluoride dichloride, Ba7F12Cl2, displaying a new 2a,c hexagonal superstructure with P-6 symmetry. The superstructure results from the disorder of Ba2+ cations over two adjacent tricapped trigonal prismatic sites located in channels parallel to the c axis.

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Key concepts: Superstructure, Hexagonal crystal system, Crystallography, Trigonal crystal system, Hydrothermal circulation, Materials science, Trigonal prismatic molecular geometry, Hydrothermal synthesis