ScholarLens Back to search
2012•OrganometallicsOpen access

Rhodium(III)-Catalyzed Hydroamination of Aromatic Terminal Alkynes with Anilines

Elumalai Kumaran, Weng Kee Leong

Open full text 40 citations

Abstract

The dinuclear Rh(III) species [Cp*RhCl 2 ] 2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH 2 ), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.

Open-access reader

About this research paper

What this paper is about

The dinuclear Rh(III) species [Cp*RhCl 2 ] 2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH 2 ), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.

Why it matters

OpenAlex reports 40 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The dinuclear Rh(III) species [Cp*RhCl 2 ] 2 catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH 2 ), in the presence of a salt additive, to afford the ketimine Ar′N═C(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies.

Key concepts: Hydroamination, Chemistry, Alkyne, Aniline, Catalysis, Rhodium, Terminal (telecommunication), Salt (chemistry)

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Rhodium(III)-Catalyzed Hydroamination of Aromatic Terminal Alkynes with Anilines — Research Paper | ScholarLens