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2003•Journal of the American Chemical SocietyRequires access

Formation of Bridging Alkene and Conjugated Dialkenes Exclusively Generated from Alkynes on the [3,3‘-Co(1,2-C2B9H11)2]- Platform. The Unique Hydroboration Role of [3,3‘-Co(1,2-C2B9H11)2]-

I. Rojo, Francesç Teixidor, Raikko Kivekäs, Reijo Sillanpää, Clara Viñas

Open publisher page 55 citations

Abstract

The unprecedented metal-mediated transformation of an alkyne into a B,B' bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3'-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B-H to produce hydroboration.

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What this paper is about

The unprecedented metal-mediated transformation of an alkyne into a B,B' bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3'-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B-H to produce hydroboration.

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OpenAlex reports 55 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

The unprecedented metal-mediated transformation of an alkyne into a B,B' bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3'-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B-H to produce hydroboration.

Key concepts: Chemistry, Alkene, Conjugated system, Bridging (networking), Alkyne, Stereochemistry, Organic chemistry, Catalysis

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Formation of Bridging Alkene and Conjugated Dialkenes Exclusively Generated from Alkynes on the [3,3‘-Co(1,2-C2B9H11)2]- Platform. The Unique Hydroboration Role of [3,3‘-Co(1,2-C2B9H11)2]- — Research Paper | ScholarLens