1989•Chemical and Pharmaceutical BulletinOpen access

Stereospecific nuclephilic addition reaction of thiophenol to .ALPHA.,.BETA.-unsaturated esters.

Okiko Miyata, Tetsuro Shinada, Takeaki Naito, Ichiya Ninomiya

Abstract

A concerted method for the stereospecific addition of thiophenol to α, β-unsaturated esters 1 and 3 has been developed. This provides a convenient route for the stereo-selective preparation of less available Z__--α, β-unsaturated esters and lactones 3.

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Key concepts: Thiophenol, Chemistry, Stereospecificity, Organic chemistry, Alpha (finance), BETA (programming language), Stereochemistry, Catalysis