Diterpenoids. IX. Chemical Conversion to Diterpene Alkaloid from Abietic Acid.
Akira Tahara, Ken‐ichi Hirao
Abstract
Open-access reader
Akira Tahara, Ken‐ichi Hirao
Abstract
Open-access reader
By confluence from l-abietic acid at the key intermediate (XXIV) for Nagata's total synthesis of dl-atisine (I), dl-veatchine (II) and dl-garryine (III), the first example of total synthesis of the natural diterpene alkaloid from the other natural diterpene, was accomplished.
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By confluence from l-abietic acid at the key intermediate (XXIV) for Nagata's total synthesis of dl-atisine (I), dl-veatchine (II) and dl-garryine (III), the first example of total synthesis of the natural diterpene alkaloid from the other natural diterpene, was accomplished.
Key concepts: Abietic acid, Diterpene, Chemistry, Alkaloid, Stereochemistry, Abietane, Organic chemistry, Resin acid