Constituents of Zingiberaceae. I. Diarylheptanoids from the rhizomes of ginger (Zingiber officinale Roscoe).
Hiroe Kikuzaki, Junko USUGUCHI, Nobuji Nakatani
Abstract
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Hiroe Kikuzaki, Junko USUGUCHI, Nobuji Nakatani
Abstract
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Two new diarylheptanoids, meso-3, 5-diacetoxy-1, 7-bis(4-hydroxy-3-methoxyphenyl)heptane (3a) and 3, 5-diacetoxy-1-(4-hydroxy-3, 5-dimethoxyphenyl)-7-(4-hydroxy-3-methoxyphenyl)heptane (4a) were isolated from the rhizomes of ginger (Zingiber officinale ROSCOE), together with dehydroxytetrahydrocurcumin (gingerenone A, 1) and hexahydrocurcumin (2). Their structures were elucidated on the basis of chemical and spectroscopic evidence.
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Two new diarylheptanoids, meso-3, 5-diacetoxy-1, 7-bis(4-hydroxy-3-methoxyphenyl)heptane (3a) and 3, 5-diacetoxy-1-(4-hydroxy-3, 5-dimethoxyphenyl)-7-(4-hydroxy-3-methoxyphenyl)heptane (4a) were isolated from the rhizomes of ginger (Zingiber officinale ROSCOE), together with dehydroxytetrahydrocurcumin (gingerenone A, 1) and hexahydrocurcumin (2). Their structures were elucidated on the basis of chemical and spectroscopic evidence.
Key concepts: Diarylheptanoids, Zingiber officinale, Zingiberaceae, Rhizome, Chemistry, Traditional medicine, Heptane, Stereochemistry