BETA RADIATION PROCESSING AT RIGOROUS CONDITIONS
Paul M. Yavorsky, E. Gorin
Abstract
Paul M. Yavorsky, E. Gorin
Abstract
An investigation was conducted on the impossible use of beta radiation to promote chemical reactions at high temperatures and pressures. The advantages of beta sources over other radiation sources are enumerated. A radiation processing apparatus is described which allows operations to 10,000 psi and 500 deg C and uses 90 C of Sr/sup 90/-Y/sup 90/. The dosimetry of the source was accomplished with an iodineheptane system, and the mean dose rate within the chemical reactor was determined to be 0.98 x 10/sup 6/ rad/hr. The radiation utilization efficiency in the dosimetry measurements was determined to be 34.7%. Results of runs on hydrogenation of coal extract indicate that radiation does not increase the extent of hydrogenation, but that radiation reduces the content of hetero atoms N and S in the 100 x 400 deg C boiling oil products. The use of beta radiation in the hydrorefining of oils is suggested. (D.L.C.)
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An investigation was conducted on the impossible use of beta radiation to promote chemical reactions at high temperatures and pressures. The advantages of beta sources over other radiation sources are enumerated. A radiation processing apparatus is described which allows operations to 10,000 psi and 500 deg C and uses 90 C of Sr/sup 90/-Y/sup 90/. The dosimetry of the source was accomplished with an iodineheptane system, and the mean dose rate within the chemical reactor was determined to be 0.98 x 10/sup 6/ rad/hr. The radiation utilization efficiency in the dosimetry measurements was determined to be 34.7%. Results of runs on hydrogenation of coal extract indicate that radiation does not increase the extent of hydrogenation, but that radiation reduces the content of hetero atoms N and S in the 100 x 400 deg C boiling oil products. The use of beta radiation in the hydrorefining of oils is suggested. (D.L.C.)
Key concepts: Radiation, Dosimetry, Radiochemistry, Beta particle, Radiation dose, Irradiation, Ionizing radiation, Materials science