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SODIUM FLUID DYNAMICS.

Battelle-Northwest, Richland, Wash. Pacific Northwest Lab. Colorado State Univ., Fort Collins. Dept. of Radiology and Radiation Biology, Andrew Padilla

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Abstract

of sodium chloride (NaCl) solutions can provide a basis for those of NaNO{sub 3} solutions, we also present a comparison of thermophysical properties of both salt solutions. We have implemented the functional thermophysical properties of NaNO{sub 3} solutions into a new TOUGH2 equation-of-state module EWASG-NaNO{sub 3}, which is modified from a previous TOUGH2 equation-of-state module EWASG for NaCl. Using the simulation tool, we have investigated effects of the thermophysical properties on fluid flow in unsaturated media. The effect of density and viscosity of saline solutions has been long recognized. Here we focus our attention on the effect of vapor pressure lowering due to salinity. We present simulations of a one-dimensional problem to study this salinity-driven fluid flow. A number of simulations were performed using different values of thermal conductivity, permeability, and temperature, to illustrate conditions and parameters controlling these processes. Results indicate that heat conduction plays a very important role in this salinity-driven vapor diffusion by maintaining a nearly constant temperature. The smaller the permeability, the more water is transferred into the saline environment. Effects of permeability on water flow are also complicated by effects of capillary pressure and tortuosity. The higher the temperature, the more significant the salinity driven fluid flow.

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of sodium chloride (NaCl) solutions can provide a basis for those of NaNO{sub 3} solutions, we also present a comparison of thermophysical properties of both salt solutions. We have implemented the functional thermophysical properties of NaNO{sub 3} solutions into a new TOUGH2 equation-of-state module EWASG-NaNO{sub 3}, which is modified from a previous TOUGH2 equation-of-state module EWASG for NaCl. Using the simulation tool, we have investigated effects of the thermophysical properties on fluid flow in unsaturated media. The effect of density and viscosity of saline solutions has been long recognized. Here we focus our attention on the effect of vapor pressure lowering due to salinity. We present simulations of a one-dimensional problem to study this salinity-driven fluid flow. A number of simulations were performed using different values of thermal conductivity, permeability, and temperature, to illustrate conditions and parameters controlling these processes. Results indicate that heat conduction plays a very important role in this salinity-driven vapor diffusion by maintaining a nearly constant temperature. The smaller the permeability, the more water is transferred into the saline environment. Effects of permeability on water flow are also complicated by effects of capillary pressure and tortuosity. The higher the temperature, the more significant the salinity driven fluid flow.

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Available abstract

of sodium chloride (NaCl) solutions can provide a basis for those of NaNO{sub 3} solutions, we also present a comparison of thermophysical properties of both salt solutions. We have implemented the functional thermophysical properties of NaNO{sub 3} solutions into a new TOUGH2 equation-of-state module EWASG-NaNO{sub 3}, which is modified from a previous TOUGH2 equation-of-state module EWASG for NaCl. Using the simulation tool, we have investigated effects of the thermophysical properties on fluid flow in unsaturated media. The effect of density and viscosity of saline solutions has been long recognized. Here we focus our attention on the effect of vapor pressure lowering due to salinity. We present simulations of a one-dimensional problem to study this salinity-driven fluid flow. A number of simulations were performed using different values of thermal conductivity, permeability, and temperature, to illustrate conditions and parameters controlling these processes. Results indicate that heat conduction plays a very important role in this salinity-driven vapor diffusion by maintaining a nearly constant temperature. The smaller the permeability, the more water is transferred into the saline environment. Effects of permeability on water flow are also complicated by effects of capillary pressure and tortuosity. The higher the temperature, the more significant the salinity driven fluid flow.

Key concepts: Salinity, Tortuosity, Thermal conductivity, Thermodynamics, Thermal conduction, Permeability (electromagnetism), Sodium, Chemistry

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